You could build a C# mail client for Hotmail - the world's first web-based email service - if only you knew what Hotmail expects as requests and how it responds.
Here is what can help you do just that:
http://www.thecodeproject.com/csharp/httpmail.asp?df=100&forumid=14989&exp=0&select=583615
Really amazing article.
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Disclaimer The opinions expressed herein are my own personal opinions and do not represent the views of Microsoft Corporation in anyway.